Search results for " table"

Preparation and crystal structure of the oxalato-bridged CrIII–AgItwo-dimensional compound {Ag3(H2O)[Cr(dpa)(ox)2]3}n·2nH2O (dpa = 2,2′-dipyridylamin…

2004

The reaction of the mononuclear complex [Cr(dpa)(ox)2]− (dpa = 2,2-dipyridylamine) with Ag+ in aqueous solution affords the two-dimensional compound {Ag3(H2O)[Cr(dpa)(ox)2]3}n·2nH2O (1) whose structure has been determined by single-crystal X-ray diffraction. Six crystallographically independent metal atoms (three chromium and three silver atoms) occur in 1. The three [Cr(dpa)(ox)2]− units in 1 act as ligands towards the silver atoms through the two oxalate groups. Each oxalate group acts as bridging ligand adopting five coordination modes: bis-bidentate, bis-bidentate/monodentate (outer), bis-bidentate/monodentate (inner), bidentate/bis-monodentate (outer) and bidentate/monodentate (outer).…

Hydrology is reflected in the functioning and community composition of methanotrophs in the littoral wetland of a boreal lake

2010

In lake ecosystems a major proportion of methane (CH4) emissions originate from the littoral zone, which can have a great spatial variability in hydrology, soil quality and vegetation. Hitherto, spatial heterogeneity and the effects it has on functioning and diversity of methanotrophs in littoral wetlands have been poorly understood. A diagnostic microarray based on the particulate methane monooxygenase gene coupled with geostatistics was used to analyse spatial patterns of methanotrophs in the littoral wetland of a eutrophic boreal lake (Lake Kevaton, Eastern Finland). The wetland had a hydrology gradient with a mean water table varying from −8 to −25 cm. The wettest area, comprising the h…

2018

Tetrel bonding is the noncovalent interaction of group IV elements with electron donors. It is a weak, directional interaction that resembles hydrogen and halogen bonding yet remains barely explored. Herein, we present an experimental investigation of the carbon-centered, three-center, four-electron tetrel bond, [N–C–N]+, formed by capturing a carbenium ion with a bidentate Lewis base. NMR-spectroscopic, titration-calorimetric, and reaction-kinetic evidence for the existence and structure of this species is reported. The studied interaction is by far the strongest tetrel bond reported so far and is discussed in comparison with the analogous halogen bond. The necessity of the involvement of …

The relationship between bipolar disorder and alcoholism: a controlled family study.

1995

SYNOPSISBipolar disorder and alcoholism are familial disorders. The familial–genetic relationship between both is controversial and has received insufficient study. This study explores whether bipolar disorder and alcoholism share familial risk factors, and whether the co-occurrence of lifetime diagnosis of bipolar disorder and alcoholism is familial. We report on first-degree relatives of 146 consecutively admitted patients with either bipolar disorder or/and alcoholism; relatives of the patients (in total 728 relatives directly interviewed) were compared with first-degree relatives of 109 general population probands (320 relatives directly interviewed). Overlap between the familial compon…

Fusion in the character table

1998

Suppose that P P is a Sylow p p -subgroup of a finite p p -solvable group G G . If g ∈ P g \in P , then the number of G G -conjugates of g g in P P can be read off from the character table of G G .

ChemInform Abstract: Synthesis of Sesquiterpenes via Silicon-Guided Rearrangement of Epoxydecalins

2009

A survey of the rearrangement of methyldecalins via C-5 carbocation intermediates, with special attention to the silicon-guided rearrangement of epoxydecalins is provided. A TMS group properly posi...

Kritische Bemerkungen zur Entwicklung des Sapienstypus

1953

The earliest hominid predecessors as yet known, the Australopithecines, show that the branch leading to man was separated from the group of the anthropoids as early as the Tertiary. The Australopithecines as a group show great variability. The group contains in its genetic make-up all the characteristics of the representatives of the later stages. The presence of the primitive forms of many human characteristics has led us to include in the human line of evolution only those types which have remained primitively human (Australopithecus, Steinheim, Swanscombe, Fontechevade, Piltdown).Pithecanthropus and Neanderthals are not to be considered as stages of a higher evolution but as sidebranches…

Proceedings of the Closed Round Table and Italian Consensus on Clinical Appropriateness in Oral Medicine and Oral Surgery – Part I

2019

The minimal number of characters over a normal p-subgroup

2007

Abstract If N is a normal p-subgroup of a finite group G and θ ∈ Irr ( N ) is a G-invariant irreducible character of N, then the number | Irr ( G | θ ) | of irreducible characters of G over θ is always greater than or equal to the number k p ′ ( G / N ) of conjugacy classes of G / N consisting of p ′ -elements. In this paper, we investigate when there is equality.

Approaches for the introduction of fluorinated substituents into [1,2,3]Triazolo[1,5-a]pyridines

2014

Abstract [1,2,3]Triazolo[1,5-a]pyridines functionalization with a trifluoromethyl group has been achieved for the first time using different synthetic strategies. Furthermore, these scaffolds have been employed as starting material in the synthesis of new 2,6-disubstituted pyridines containing the trifluoromethyl group, compounds that are not available using other methodologies. A fluorine-mediated triazolopyridine dimerisation is described, improving the previously known synthetic method. Preliminary studies focused on exploring triazolopyridines reactivity with electrophilic fluorine have revealed a new approach for the obtainment of imidazopyridines.